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SynchronousInitialization -> False, TrackedSymbols :> {$CellContext`NN$$, $CellContext`n$$, \ $CellContext`l$$, $CellContext`m$$, $CellContext`s$$, $CellContext`f$$, \ $CellContext`jj$$}, AutorunSequencing -> {1}}, "DefaultOptions" :> {ControllerLinking -> True}], ImageSizeCache->{417., {96., 101.}}, SingleEvaluation->True], Deinitialization:>None, DynamicModuleValues:>{}, Initialization:>({$CellContext`Nmax = 10000; $CellContext`radius[1, 0] = CompressedData[" 1:eJxt3DtwXdd1BmC8QYAv0FLtTLqkTu25p0tau1aVmaSN0zq1atVJmzRp1EZF JjOxrLEnY2nkyJJoS6EJipJIiiIJPgAQIImEWPv776wTo9DVvffcffZej/// 19r78E//+u9+8jerKysrv9hZWdn9/J9/+qPdo8WHv379d3/xzs+f/dlb77zK +z9/6/UnT8f7L8fro8U/vPnuX+7/7Ol4vb340flAr8b748X7r4f5+cEY73Dx V/s/+79vDhb/9I+v/7ann7z3w7e/+/HGdP/Hr//n2eL87XvfjNdXi78/H/D7 RX2/Pf3F+d/7i/Nh9jemGndl+tvzv8PF+W3ffDzmtzIZ5/V/f/j2+lTjPR/z ezE+Xx3j7k01f/O8O9azMca5sfiT8x8cLP7lp6+/+TjrqXncWpyb8fMn4/tH 4/XpYuX8785Yx/5Y/+Wpxlud6neni7LH9THO0Vj/6rDP+lTjWPfWdO6Wt1an 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$CellContext`Nmax/ 4}]; $CellContext`cosinus[1, 0] = Table[Random[]^(1/3), {$CellContext`i, 1, $CellContext`Nmax/ 4}]; $CellContext`prov = Table[ Random[], {$CellContext`i, 1, $CellContext`Nmax/ 4}]; $CellContext`cosinus[1, 1] = Chop[(1 - I Sqrt[3] + (1 + I Sqrt[3]) ($CellContext`prov + Sqrt[-1 + $CellContext`prov^2])^( 2/3))/(2 ($CellContext`prov + Sqrt[-1 + $CellContext`prov^2])^( 1/3))]; $CellContext`cosinus[2, 0] = Table[ Part[ FindRoot[(-4) Random[] + 5 $CellContext`u - 10 $CellContext`u^3 + 9 $CellContext`u^5 == 0, {$CellContext`u, 0, 1}], 1, 2], {$CellContext`i, 1, $CellContext`Nmax/ 4}]; $CellContext`cosinus[2, 1] = Table[ Part[ FindRoot[ 2 Random[] - 5 $CellContext`u^3 + 3 $CellContext`u^5 == 0, {$CellContext`u, 0, 1}], 1, 2], {$CellContext`i, 1, $CellContext`Nmax/4}]; $CellContext`cosinus[2, 2] = Table[ Part[ FindRoot[(-8) Random[] + 15 $CellContext`u - 10 $CellContext`u^3 + 3 $CellContext`u^5 == 0, {$CellContext`u, 0, 1}], 1, 2], {$CellContext`i, 1, $CellContext`Nmax/ 4}]; $CellContext`cosinus[3, 0] = Table[ Part[ FindRoot[(-4) Random[] + 21 $CellContext`u^3 - 42 $CellContext`u^5 + 25 $CellContext`u^7 == 0, {$CellContext`u, 0, 1}], 1, 2], {$CellContext`i, 1, $CellContext`Nmax/ 4}]; $CellContext`cosinus[3, 1] = Table[ Part[ FindRoot[ 16 Random[] - 21 $CellContext`u + 77 $CellContext`u^3 - 147 $CellContext`u^5 + 75 $CellContext`u^7 == 0, {$CellContext`u, 0, 1}], 1, 2], {$CellContext`i, 1, $CellContext`Nmax/4}]; $CellContext`cosinus[3, 2] = Table[ Part[ FindRoot[(-8) Random[] + 35 $CellContext`u^3 - 42 $CellContext`u^5 + 15 $CellContext`u^7 == 0, {$CellContext`u, 0, 1}], 1, 2], {$CellContext`i, 1, $CellContext`Nmax/ 4}]; $CellContext`cosinus[3, 3] = Table[ Part[ FindRoot[ 16 Random[] - 35 $CellContext`u + 35 $CellContext`u^3 - 21 $CellContext`u^5 + 5 $CellContext`u^7 == 0, {$CellContext`u, 0, 1}], 1, 2], {$CellContext`i, 1, $CellContext`Nmax/4}]; $CellContext`Delta1 = 0.125; $CellContext`sign = Table[2 RandomInteger[] - 1, {$CellContext`i, 1, $CellContext`Nmax}]; $CellContext`phinus = Table[(2 Pi) Random[], {$CellContext`i, 1, $CellContext`Nmax}]; $CellContext`sort1 = Table[ RandomInteger[{1, $CellContext`Nmax/4}], {$CellContext`i, 1, $CellContext`Nmax}]; $CellContext`sort2 = Table[ RandomInteger[{1, $CellContext`Nmax/4}], {$CellContext`i, 1, $CellContext`Nmax}]; For[$CellContext`nn = 1, $CellContext`nn < 5, Increment[$CellContext`nn], For[$CellContext`ll = 0, $CellContext`ll < $CellContext`nn, Increment[$CellContext`ll], For[$CellContext`mm = 0, $CellContext`mm < $CellContext`ll + 1, Increment[$CellContext`mm], $CellContext`table3D[$CellContext`nn, \ $CellContext`ll, $CellContext`mm] = Table[{(Part[ $CellContext`radius[$CellContext`nn, $CellContext`ll], Part[$CellContext`sort1, $CellContext`i]] Sqrt[1 - Part[ $CellContext`cosinus[$CellContext`ll, $CellContext`mm], Part[$CellContext`sort2, $CellContext`i]]^2]) Cos[ Part[$CellContext`phinus, $CellContext`i]], (Part[ $CellContext`radius[$CellContext`nn, $CellContext`ll], Part[$CellContext`sort1, $CellContext`i]] Sqrt[1 - Part[ $CellContext`cosinus[$CellContext`ll, $CellContext`mm], Part[$CellContext`sort2, $CellContext`i]]^2]) Sin[ Part[$CellContext`phinus, $CellContext`i]], (Part[ $CellContext`radius[$CellContext`nn, $CellContext`ll], Part[$CellContext`sort1, $CellContext`i]] Part[ $CellContext`cosinus[$CellContext`ll, $CellContext`mm], Part[$CellContext`sort2, $CellContext`i]]) Part[$CellContext`sign, $CellContext`i]}, {$CellContext`i, \ $CellContext`Nmax}]; For[$CellContext`kk = 1, $CellContext`kk < 5, Increment[$CellContext`kk], $CellContext`phi0 = $CellContext`kk ( Pi/4); $CellContext`Delta = $CellContext`nn^2 \ $CellContext`Delta1; $CellContext`i = 1; For[$CellContext`k = 1, $CellContext`k < $CellContext`Nmax + 1, Increment[$CellContext`k], If[(Part[ $CellContext`table3D[$CellContext`nn, $CellContext`ll, \ $CellContext`mm], $CellContext`k, 1]^2 + Part[ $CellContext`table3D[$CellContext`nn, $CellContext`ll, \ $CellContext`mm], $CellContext`k, 2]^2) Sin[$CellContext`phi0 - Part[$CellContext`phinus, $CellContext`k]]^2 < \ $CellContext`Delta^2, $CellContext`xx[$CellContext`i] = Sqrt[Part[ $CellContext`table3D[$CellContext`nn, $CellContext`ll, \ $CellContext`mm], $CellContext`k, 1]^2 + Part[ $CellContext`table3D[$CellContext`nn, $CellContext`ll, \ $CellContext`mm], $CellContext`k, 2]^2] Cos[$CellContext`phi0 - Part[$CellContext`phinus, $CellContext`k]]; \ $CellContext`zz[$CellContext`i] = Part[ $CellContext`table3D[$CellContext`nn, $CellContext`ll, \ $CellContext`mm], $CellContext`k, 3]; $CellContext`i = $CellContext`i + 1, $CellContext`i = $CellContext`i]]; \ $CellContext`imax[$CellContext`nn, $CellContext`ll, $CellContext`mm, \ $CellContext`kk] = $CellContext`i - 1; $CellContext`slice2D[$CellContext`nn, $CellContext`ll, \ $CellContext`mm, $CellContext`kk] = Table[{ $CellContext`xx[$CellContext`j], $CellContext`zz[$CellContext`j]}, {$CellContext`j, 1, $CellContext`imax[$CellContext`nn, $CellContext`ll, \ $CellContext`mm, $CellContext`kk]}]]]]]; $CellContext`xmax[1] = 5; $CellContext`xmax[2] = 15; $CellContext`xmax[3] = 30; $CellContext`xmax[4] = 45; $CellContext`pointsize = 0.005; $CellContext`Planes[ Pattern[$CellContext`n$, Blank[]], Pattern[$CellContext`kk$, Blank[]]] := If[$CellContext`kk$ < 5, Graphics3D[ Rotate[{Green, Opacity[0.05], Cuboid[{0, -$CellContext`xmax[$CellContext`n$], \ -$CellContext`xmax[$CellContext`n$]}, {0, $CellContext`xmax[$CellContext`n$], $CellContext`xmax[$CellContext`n$]}]}, $CellContext`kk$ (Pi/ 4), {0, 0, 1}, {0, 0, 0}], ImageSize -> {550, 350}], Graphics3D[ Table[ Rotate[{Green, Opacity[0.05], Cuboid[{0, -$CellContext`xmax[$CellContext`n$], \ -$CellContext`xmax[$CellContext`n$]}, {0, $CellContext`xmax[$CellContext`n$], $CellContext`xmax[$CellContext`n$]}]}, $CellContext`jj$$ (Pi/ 4), {0, 0, 1}, {0, 0, 0}], {$CellContext`jj$$, 1, 4}], ImageSize -> {550, 350}]]; $CellContext`View3D[ Pattern[$CellContext`n, Blank[]], Pattern[$CellContext`l, Blank[]], Pattern[$CellContext`m, Blank[]], Pattern[$CellContext`kk, Blank[]], Pattern[$CellContext`NN, Blank[]]] := If[$CellContext`kk == 0, ListPointPlot3D[ Table[ Part[ $CellContext`table3D[$CellContext`n, $CellContext`l, \ $CellContext`m], $CellContext`i], {$CellContext`i, 1, $CellContext`NN}], BoxRatios -> {1, 1, 1}, AxesLabel -> { Style["x", Italic], Style["y", Italic], Style["z", Italic]}, PlotStyle -> PointSize[$CellContext`pointsize], PlotRange -> {{-$CellContext`xmax[$CellContext`n], $CellContext`xmax[$CellContext`n]}, \ {-$CellContext`xmax[$CellContext`n], $CellContext`xmax[$CellContext`n]}, \ {-$CellContext`xmax[$CellContext`n], $CellContext`xmax[$CellContext`n]}}, ViewPoint -> {1., -2.4, 1.}, ImageSize -> {550, 350}], Show[ ListPointPlot3D[ Table[ Part[ $CellContext`table3D[$CellContext`n, $CellContext`l, \ $CellContext`m], $CellContext`i], {$CellContext`i, 1, $CellContext`NN}], BoxRatios -> {1, 1, 1}, AxesLabel -> { Style["x", Italic], Style["y", Italic], Style["z", Italic]}, PlotStyle -> PointSize[$CellContext`pointsize], PlotRange -> {{-$CellContext`xmax[$CellContext`n], $CellContext`xmax[$CellContext`n]}, \ {-$CellContext`xmax[$CellContext`n], $CellContext`xmax[$CellContext`n]}, \ {-$CellContext`xmax[$CellContext`n], $CellContext`xmax[$CellContext`n]}}, ViewPoint -> {1., -2.4, 1.}, ImageSize -> {550, 350}], $CellContext`Planes[$CellContext`n, $CellContext`kk]]]; \ $CellContext`hue = {0.1, 0.3, 0.7, 0.9}; $CellContext`ViewSlice[ Pattern[$CellContext`n$, Blank[]], Pattern[$CellContext`l$, Blank[]], Pattern[$CellContext`m$, Blank[]], Pattern[$CellContext`kk$, Blank[]], Pattern[$CellContext`NN$, Blank[]]] := If[$CellContext`kk$ == 0, Style["Choose an orientation!", 30], If[$CellContext`kk$ < 5, ListPlot[ Table[ Part[ $CellContext`slice2D[$CellContext`n$, $CellContext`l$, \ $CellContext`m$, $CellContext`kk$], $CellContext`i], {$CellContext`i, 1, $CellContext`imax[$CellContext`n$, $CellContext`l$, \ $CellContext`m$, $CellContext`kk$] ($CellContext`NN$/$CellContext`Nmax)}], AspectRatio -> 1, PlotStyle -> { PointSize[$CellContext`pointsize], Hue[ Part[$CellContext`hue, $CellContext`kk$]]}, PlotRange -> {{-$CellContext`xmax[$CellContext`n$], $CellContext`xmax[$CellContext`n$]}, \ {-$CellContext`xmax[$CellContext`n$], $CellContext`xmax[$CellContext`n$]}}, AxesLabel -> { Derivative[1][ Style["x", Italic]], Style["z", Italic]}, ImageSize -> {550, 350}], Show[ Table[ $CellContext`ViewSlice[$CellContext`n$, $CellContext`l$, \ $CellContext`m$, $CellContext`jj$$, $CellContext`NN$], {$CellContext`jj$$, 1, 4}]]]]; $CellContext`View[ Pattern[$CellContext`n, Blank[]], Pattern[$CellContext`l, Blank[]], Pattern[$CellContext`m, Blank[]], Pattern[$CellContext`kk, Blank[]], Pattern[$CellContext`NN, Blank[]], Pattern[$CellContext`f, Blank[]]] := If[$CellContext`f == 1, $CellContext`View3D[$CellContext`n, $CellContext`l, $CellContext`m, \ $CellContext`kk, $CellContext`NN], $CellContext`ViewSlice[$CellContext`n, $CellContext`l, \ $CellContext`m, $CellContext`kk, $CellContext`NN]]; $CellContext`Viewoverm[ Pattern[$CellContext`n, Blank[]], Pattern[$CellContext`l, Blank[]], Pattern[$CellContext`kk, Blank[]], Pattern[$CellContext`NN, Blank[]], Pattern[$CellContext`f, Blank[]]] := If[ And[$CellContext`kk == 0, $CellContext`f == 2], Style["Choose an orientation!", 30], If[$CellContext`l == 0, $CellContext`View[$CellContext`n, 0, 0, $CellContext`kk, $CellContext`NN, $CellContext`f], Show[ $CellContext`View[$CellContext`n, $CellContext`l, 0, $CellContext`kk, $CellContext`NN/2, $CellContext`f], Table[ $CellContext`View[$CellContext`n, $CellContext`l, \ $CellContext`ml, $CellContext`kk, $CellContext`NN, $CellContext`f], \ {$CellContext`ml, 1, $CellContext`l}]]]]}; Typeset`initDone$$ = True), SynchronousInitialization->False, UnsavedVariables:>{Typeset`initDone$$}, UntrackedVariables:>{Typeset`size$$}], "Manipulate", Deployed->True, StripOnInput->False], Manipulate`InterpretManipulate[1]]], "Output", CellID->1231427601], Cell[TextData[{ "The main goal of this Demonstration is to plot 3D density clouds of the \ position of the electron in the hydrogen atom in states defined by the three \ quantum numbers ", Cell[BoxData[ FormBox["n", TraditionalForm]], "InlineMath"], " (principal), ", Cell[BoxData[ FormBox["l", TraditionalForm]], "InlineMath"], " (azimuthal), and ", Cell[BoxData[ FormBox["m", TraditionalForm]], "InlineMath"], " (magnetic). Each dot of the cloud represents a possible result of a \ measurement of the position of the electron in an individual atom. By \ imagining that the measurement is repeated many times in different atoms at \ the same quantum state, you can get a plot representing the probability \ density function associated with that state. A 2D view can also be obtained \ by a plane slice containing the ", Cell[BoxData[ FormBox["z", TraditionalForm]], "InlineMath"], " axis. You can select the number of position measurements to be simulated, \ the quantum numbers ", Cell[BoxData[ FormBox["n", TraditionalForm]], "InlineMath"], ", ", Cell[BoxData[ FormBox["l", TraditionalForm]], "InlineMath"], ", and ", Cell[BoxData[ FormBox[ RowBox[{"|", "m", "|"}], TraditionalForm]], "InlineMath"], " (or all values of ", Cell[BoxData[ FormBox["m", TraditionalForm]], "InlineMath"], " combined in a single plot), and the type of view (3D or 2D). In the 2D \ slice view you can choose the slice orientation (four possibilities) or all \ four slices combined for better statistics. The length unit is set equal to \ the Bohr radius." }], "ManipulateCaption", CellID->1315744102], Cell["THINGS TO TRY", "ManipulateCaption", CellFrame->{{0, 0}, {1, 0}}, CellFrameColor->RGBColor[0.87, 0.87, 0.87], FontFamily->"Helvetica", FontSize->12, FontWeight->"Bold", FontColor->RGBColor[0.597406, 0, 0.0527047], CellTags->"ControlSuggestions"], Cell[TextData[{ Cell[BoxData[ TooltipBox[ PaneSelectorBox[{False->Cell[TextData[StyleBox["Resize Images", FontFamily->"Verdana"]]], True->Cell[TextData[StyleBox["Resize Images", FontFamily->"Verdana", FontColor->GrayLevel[0.5]]]]}, Dynamic[ CurrentValue["MouseOver"]]], "\"Click inside an image to reveal its orange resize frame.\\nDrag any of \ the orange resize handles to resize the image.\"", TooltipStyle->{ FontFamily -> "Verdana", FontSize -> 10, FontColor -> GrayLevel[0.35], Background -> GrayLevel[0.98]}]]], StyleBox["\[NonBreakingSpace]\[FilledVerySmallSquare]\[NonBreakingSpace]", FontColor->RGBColor[0.928786, 0.43122, 0.104662]], Cell[BoxData[ TooltipBox[ PaneSelectorBox[{False->Cell[TextData[StyleBox["Rotate and Zoom in 3D", FontFamily->"Verdana"]]], True->Cell[TextData[StyleBox[ "Rotate and Zoom in 3D", FontFamily->"Verdana", FontColor->GrayLevel[0.5]]]]}, Dynamic[ CurrentValue["MouseOver"]]], RowBox[{ "\"Drag a 3D graphic to rotate it. Starting the drag near the center \ tumbles\\nthe graphic; starting near a corner turns it parallel to the plane \ of the screen.\\nHold down \"", FrameBox[ "Ctrl", Background -> GrayLevel[0.9], FrameMargins -> 2, FrameStyle -> GrayLevel[0.9]], "\" (or \"", FrameBox[ "Cmd", Background -> GrayLevel[0.9], FrameMargins -> 2, FrameStyle -> GrayLevel[0.9]], "\" on Mac) and drag up and down to zoom.\""}], TooltipStyle->{ FontFamily -> "Verdana", FontSize -> 10, FontColor -> GrayLevel[0.35], Background -> GrayLevel[0.98]}]]], StyleBox["\[NonBreakingSpace]\[FilledVerySmallSquare]\[NonBreakingSpace]", FontColor->RGBColor[0.928786, 0.43122, 0.104662]], Cell[BoxData[ TooltipBox[ PaneSelectorBox[{False->Cell[TextData[StyleBox["Slider Zoom", FontFamily->"Verdana"]]], True->Cell[TextData[StyleBox["Slider Zoom", FontFamily->"Verdana", FontColor->GrayLevel[0.5]]]]}, Dynamic[ CurrentValue["MouseOver"]]], RowBox[{"\"Hold down the \"", FrameBox[ "Alt", Background -> GrayLevel[0.9], FrameMargins -> 2, FrameStyle -> GrayLevel[0.9]], "\" key while moving a slider to make fine adjustments in the slider \ value.\\nHold \"", FrameBox[ "Ctrl", Background -> GrayLevel[0.9], FrameMargins -> 2, FrameStyle -> GrayLevel[0.9]], "\" and/or \"", FrameBox[ "Shift", Background -> GrayLevel[0.9], FrameMargins -> 2, FrameStyle -> GrayLevel[0.9]], "\" at the same time as \"", FrameBox[ "Alt", Background -> GrayLevel[0.9], FrameMargins -> 2, FrameStyle -> GrayLevel[0.9]], "\" to make ever finer adjustments.\""}], TooltipStyle->{ FontFamily -> "Verdana", FontSize -> 10, FontColor -> GrayLevel[0.35], Background -> GrayLevel[0.98]}]]], StyleBox["\[NonBreakingSpace]\[FilledVerySmallSquare]\[NonBreakingSpace]", FontColor->RGBColor[0.928786, 0.43122, 0.104662]], Cell[BoxData[ TooltipBox[ PaneSelectorBox[{False->Cell[TextData[StyleBox["Automatic Animation", FontFamily->"Verdana"]]], True->Cell[TextData[StyleBox[ "Automatic Animation", FontFamily->"Verdana", FontColor->GrayLevel[0.5]]]]}, Dynamic[ 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SubscriptBox["N", RowBox[{"n", "\[InvisibleSpace]", "l"}]], TraditionalForm]], "InlineMath"], " is a normalization constant and ", Cell[BoxData[ FormBox[ RowBox[{ SubsuperscriptBox["L", RowBox[{"n", "-", "l", "-", "1"}], RowBox[{ RowBox[{"2", "l"}], "+", "1"}]], "(", "x", ")"}], TraditionalForm]], "InlineMath"], " is a generalized Laguerre polynomial. The probability density function,", Cell[BoxData[ FormBox[ RowBox[{"|", RowBox[{ SubscriptBox["\[CapitalPsi]", RowBox[{"n", "\[InvisibleSpace]", "l", "\[InvisibleSpace]", "m"}]], "(", RowBox[{"r", ",", "\[Theta]", ",", "\[Phi]"}], ")"}], SuperscriptBox["|", "2"]}], TraditionalForm]], "InlineMath"], ", is independent of ", Cell[BoxData[ FormBox["\[Phi]", TraditionalForm]], "InlineMath"], " and of the sign of ", Cell[BoxData[ FormBox["m", TraditionalForm]], "InlineMath"], "." }], "DetailNotes", CellID->436236890], Cell["Reference", "DetailNotes", CellID->209465641], Cell[TextData[{ "[1] R. Eisberg and R. 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